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Abstract A range of stellar explosions, including supernovae (SNe), tidal disruption events (TDE), and fast blue optical transients (FBOTs), can occur in dusty environments initially opaque to transients’ optical/UV light, becoming visible only once the dust is destroyed by transients’ rising luminosity. We present axisymmetric, time-dependent radiation transport simulations of dust-shrouded transients withAthena++and tabulated gray opacities, predicting the light curves of the dust-reprocessed infrared (IR) radiation. The luminosity and timescale of the IR light curve depend on whether the transient rises rapidly or slowly compared to the light-crossing time of the photosphere,t_lc. For slow-rising transients (t_rise ≫ t_lc) like SNe, the reprocessed IR radiation diffuses outward through the dust shell faster than the shell sublimates; the IR light curve therefore begins rising prior to the escape of UV/optical light, but peaks on a timescale ∼t_riseshorter than the transient duration. By contrast, for fast-rising transients (t_rise ≪ t_lc) such as FBOTs and some TDEs, the finite light-travel time results in the reprocessed radiation arriving as an “echo” lasting much longer than the transient itself. We explore the effects of the system geometry by considering a torus-shaped distribution of dust. The IR light curves seen by observers in the equatorial plane of the torus resemble those for a spherical dust shell, while polar observers see faster-rising, brighter, and shorter-lived emission. We successfully model the IR excess seen in AT2018cow as a dust echo, supporting the presence of an opaque dusty medium surrounding FBOTs prior to explosion. 

Abstract Disk continuum reverberation mapping is one of the primary ways we learn about active galactic nuclei (AGN) accretion disks. Reverberation mapping assumes that time-varying X-rays incident on the accretion disk drive variability in UV–optical light curves emitted by AGN disks and uses lags between X-ray and UV–optical variability on the light-crossing timescale to measure the radial temperature profile and extent of AGN disks. However, recent reverberation mapping campaigns have revealed oddities in some sources, such as weakly correlated X-ray and UV light curves, longer than anticipated lags, and evidence of intrinsic variability from disk fluctuations. To understand how X-ray reverberation works with realistic accretion disk structures, we perform 3D multifrequency radiation magnetohydrodynamic simulations of X-ray reprocessing by the UV-emitting region of an AGN disk using sophisticated opacity models that include line opacities for both the X-ray and UV radiation. We find there are two important factors that determine whether X-ray irradiation and UV emission will be well-correlated: the ratio of X-ray to UV luminosity and significant absorption. When these factors are met, the reprocessing of X-rays into UV is nearly instantaneous, as is often assumed, although linear reprocessing models are insufficient to fully capture X-ray reprocessing in our simulations. Nevertheless, we can still easily recover mock lags in our light curves using software that assumes linear reprocessing. Finally, the X-rays in our simulation heat the disk, increasing temperatures by a factor of 2–5 in the optically thin region, which could help explain the discrepancy between measured and anticipated lags. 

This review provides an overview of the fabrication methods for Ti3C2Tx MXene-based hybrid photocatalysts and evaluates their role in degrading organic dye pollutants. Ti3C2Tx MXene has emerged as a promising material for hybrid photocatalysts due to its high metallic conductivity, excellent hydrophilicity, strong molecular adsorption, and efficient charge transfer. These properties facilitate faster charge separation and minimize electron–hole recombination, leading to exceptional photodegradation performance, long-term stability, and significant attention in dye degradation applications. Ti3C2Tx MXene-based hybrid photocatalysts significantly improve dye degradation efficiency, as evidenced by higher percentage degradation and reduced degradation time compared to conventional semiconducting materials. This review also highlights computational techniques employed to assess and enhance the performance of Ti3C2Tx MXene-based hybrid photocatalysts for dye degradation. It identifies the challenges associated with Ti3C2Tx MXene-based hybrid photocatalyst research and proposes potential solutions, outlining future research directions to address these obstacles effectively. 

This study investigates the synergistic properties of 2D/1D ReS2-decorated LaFeO3 nanohybrids, presenting a unique approach to photocatalytic dye degradation. Through facile hydrothermal synthesis, we fabricated these nanohybrids with varying ReS2 loadings. Notably, the 5 wt% ReS2-LaFeO3 nanohybrid exhibited highly efficient visible-light-driven photocatalytic degradation of Congo red (CR) dye, achieving 82% degradation within 180 min. This enhanced performance can be attributed to synergistic effects arising from the unique 2D/1D architecture and the modified charge-transfer properties within the 2D/1D ReS2-LaFeO3 heterostructure. These findings demonstrate the potential of these multifunctional nanohybrids for applications in environmental remediation. 

This study evaluates the critical roles of the dispersion medium and temperature during the solvothermal synthesis of nitrogen-doped reduced graphene oxide (NG) for enhancing its performance as an active material in supercapacitor electrodes. Using a fixed volume of a solvent (THF, ethanol, acetonitrile, water, N,N-Dimethylformamide, ethylene glycol, or N-Methyl-2-pyrrolidone) as the dispersive medium, a series of samples at different temperatures (60, 75, 95, 120, 150, 180, and 195 °C) are synthesized and investigated. A proper removal of the oxygen moieties from their surface and an optimum number of N-based defects are essential for a better reduction of graphene oxide and better stacking of the NG sheets. The origin of the supercapacitance of NG sheets can be correlated to the inherent properties such as the boiling point, viscosity, dipole moment, and dielectric constant of all the studied solvents, along with the synthesis temperature. Due to the achievement of a suitable synthesis environment, NG synthesized using N,N-Dimethylformamide at 150 °C displays an excellent supercapacitance value of 514 F/g at 0.5 A/g, which is the highest among all our samples and also competitive among several state-of-the-art lightweight carbon materials. Our work not only helps in understanding the origin of the supercapacitance exhibited by graphene-based materials but also tuning them through a suitable choice of synthesis conditions. 

This study investigates the underlying mechanisms of hydrogen peroxide (H₂O₂) sensing using a composite material of bismuth oxide and bismuth oxyselenide (Bi2OxSey). The antagonistic effect of tungsten (W)-doping on the electrochemical behavior was also examined. Undoped, 2 mol%, 4 mol%, and 6 mol% W-doped Bi2OxSey nanostructures were synthesized using a one-pot solution phase method involving selenium powder and hydrazine hydrate. W-doping induced a morphological transformation from nanosheets to spherical nanoparticles and amorphization of the bismuth oxyselenide phase. Electrochemical sensing measurements were conducted using cyclic voltammetry (CV) and differential pulse voltammetry (DPV). H₂O₂ detection was achieved over a wide concentration range of 0.02 to 410 µM. In-depth CV analysis revealed the complex interplay of oxidation-reduction processes within the bismuth oxide and Bi2O2Se components of the composite material. W-doping exhibited an antagonistic effect, significantly reducing sensitivity. Among the studied samples, undoped Bi2OxSeγ demonstrated a high sensitivity of 83 μA μM⁻1 cm⁻2 for the CV oxidation peak at 0 V, while 6 mol% W-Bi2OxSey became completely insensitive to H2O2. Interestingly, DPV analysis showed a reversal of sensitivity trends with 2 and 4 mol% W-doping. The applicability of these samples for real-world analysis, including rainwater and urine, was also demonstrated. 

The development of high-performance hydrogen peroxide (H2O2) sensors is critical for various applications, including environmental monitoring, industrial processes, and biomedical diagnostics. This study explores the development of efficient and selective H2O2 sensors based on bismuth oxide/bismuth oxyselenide (Bi2O3/Bi2O2Se) nanocomposites. The Bi2O3/Bi2O2Se nanocomposites were synthesized using a simple solution-processing method at room temperature, resulting in a unique heterostructure with remarkable electrochemical characteristics for H2O2 detection. Characterization techniques, including powder X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM), confirmed the successful formation of the nanocomposites and their structural integrity. The synthesis time was varied to obtain the composites with different Se contents. The end goal was to obtain phase pure Bi2O2Se. Electrochemical measurements revealed that the Bi2O3/Bi2O2Se composite formed under optimal synthesis conditions displayed high sensitivity (75.7 µA µM−1 cm−2) and excellent selectivity towards H2O2 detection, along with a wide linear detection range (0–15 µM). The superior performance is attributed to the synergistic effect between Bi2O3 and Bi2O2Se, enhancing electron transfer and creating more active sites for H2O2 oxidation. These findings suggest that Bi2O3/Bi2O2Se nanocomposites hold great potential as advanced H2O2 sensors for practical applications. 

This minireview explores the unique properties and potential applications of bismuth oxychalcogenide nanosheets in chemical and biological sensing, and photodetection.